{"name": "物理有机化学", "children": [{"name": "反应机理", "children": [{"name": "[反应]机理", "en": "[reaction] mechanism", "superfield": "化学"}, {"name": "[取代基的]电子效应", "en": "electronic effect [of substituent]", "superfield": "化学"}, {"name": "[溶剂]极性", "en": "[solvent] polarity", "superfield": "化学"}, {"name": "[离子对]内部返回", "en": "internal return", "superfield": "化学"}, {"name": "[离子对]外部返回", "en": "external return", "superfield": "化学"}, {"name": "α效应", "en": "α-effect", "superfield": "化学"}, {"name": "π烯丙型络合机理", "en": "π-allyl complex mechanism", "superfield": "化学"}, {"name": "一级同位素效应", "en": "primary isotope effect", "superfield": "化学"}, {"name": "三价碳正离子", "en": "carbenium ion", "superfield": "化学"}, {"name": "中间体", "en": "intermediate", "superfield": "化学"}, {"name": "二氮烯基自由基", "en": "diazenyl radical", "superfield": "化学"}, {"name": "二级同位素效应", "en": "secondary isotope effect", "superfield": "化学"}, {"name": "亲核体", "en": "nucleophile", "superfield": "化学"}, {"name": "亲核反应", "en": "nucleophilic reaction", "superfield": "化学"}, {"name": "亲核取代[反应]", "en": "nucleophilic substitution [reaction]", "superfield": "化学"}, {"name": "亲核替取代[反应]", "en": "vicarious nucleophilic substitution [reaction]", "superfield": "化学"}, {"name": "亲电加成[反应]", "en": "electrophilic addition [reaction]", "superfield": "化学"}, {"name": "亲电取代[反应]", "en": "electrophilic substitution [reaction]", "superfield": "化学"}, {"name": "亲电性", "en": "electrophilicity", "superfield": "化学"}, {"name": "假酸", "en": "pseudo acid", "superfield": "化学"}]}, {"name": "有机化合物一般结构原理", "children": [{"name": "三角型杂化", "en": "trigonal hybridization", "superfield": "化学"}, {"name": "中环", "en": "medium ring", "superfield": "化学"}, {"name": "互变异构[现象]", "en": "tautomerism", "superfield": "化学"}, {"name": "互变异构化", "en": "tautomerization", "superfield": "化学"}, {"name": "亚烷基", "en": "alkylidene group", "superfield": "化学"}, {"name": "亚胺-烯胺互变异构", "en": "imine-enamine tautomerism", "superfield": "化学"}, {"name": "交叉共轭", "en": "cross conjugation", "superfield": "化学"}, {"name": "交替烃", "en": "alternant hydrocarbon", "superfield": "化学"}, {"name": "价互变异构", "en": "valence tautomerism", "superfield": "化学"}, {"name": "八面体化合物", "en": "octahedral compound", "superfield": "化学"}, {"name": "共振效应", "en": "resonance effect", "superfield": "化学"}, {"name": "共振论", "en": "resonance theory", "superfield": "化学"}, {"name": "共轭", "en": "conju gation", "superfield": "化学"}, {"name": "共轭体系", "en": "conjugated system", "superfield": "化学"}, {"name": "共轭分子", "en": "conjugation molecule", "superfield": "化学"}, {"name": "内张力", "en": "I strain", "superfield": "化学"}, {"name": "分子轨道法", "en": "molecular orbital method", "superfield": "化学"}, {"name": "前张力", "en": "F strain", "superfield": "化学"}, {"name": "原位进攻", "en": "ipso-attack", "superfield": "化学"}, {"name": "反芳香性", "en": "antiaromaticity", "superfield": "化学"}]}, {"name": "有机立体化学", "children": [{"name": "CIP顺序规则", "en": "Cahn-Ingold-Prelog sequence rule", "superfield": "化学"}, {"name": "D-L命名体系", "en": "D-L system of nomenclature", "superfield": "化学"}, {"name": "E异构体", "en": "E isomer", "superfield": "化学"}, {"name": "R-S命名体系", "en": "R-S system of nomenclature", "superfield": "化学"}, {"name": "Z-E异构体", "en": "Z-E isomer", "superfield": "化学"}, {"name": "Z异构体", "en": "Z isomer", "superfield": "化学"}, {"name": "re面", "en": "re-face", "superfield": "化学"}, {"name": "si面", "en": "si-face", "superfield": "化学"}, {"name": "不对称原子", "en": "asymmetric atom", "superfield": "化学"}, {"name": "不对称碳原子", "en": "asymmetric carbon", "superfield": "化学"}, {"name": "不对称转化", "en": "asymmetric transformation", "superfield": "化学"}, {"name": "二面角", "en": "dihedral angle", "superfield": "化学"}, {"name": "似外消旋体", "en": "quasi-racemate", "superfield": "化学"}, {"name": "似外消旋化合物", "en": "quasi-racemic com pound", "superfield": "化学"}, {"name": "似对映体", "en": "quasi-enantiomer", "superfield": "化学"}, {"name": "似平伏键", "en": "quasi-equatorial bond ， pseudo-equatorial bond", "superfield": "化学"}, {"name": "似直立键", "en": "quasi-axial bond", "superfield": "化学"}, {"name": "位阻", "en": "steric hindrance", "superfield": "化学"}, {"name": "信封型构象", "en": "envelope conformation", "superfield": "化学"}, {"name": "假不对称碳", "en": "pseudoasymmetric carbon", "superfield": "化学"}]}, {"name": "超分子", "children": [{"name": "π-π堆积作用", "en": "π-π stacking", "superfield": "化学"}, {"name": "两亲体", "en": "amphiphile", "superfield": "化学"}, {"name": "两可[的]", "en": "ambident", "superfield": "化学"}, {"name": "主体", "en": "host", "superfield": "化学"}, {"name": "主客体化学", "en": "host-guest chemistry", "superfield": "化学"}, {"name": "亲水[的]", "en": "hydrophilic", "superfield": "化学"}, {"name": "亲水作用", "en": "hydrophilic interaction", "superfield": "化学"}, {"name": "亲脂作用", "en": "lipophilic interaction", "superfield": "化学"}, {"name": "仿生[的]", "en": "biomimetic", "superfield": "化学"}, {"name": "分子带", "en": "molecular ribbon", "superfield": "化学"}, {"name": "分子探针", "en": "molecular probe", "superfield": "化学"}, {"name": "分子机器", "en": "molecular machine", "superfield": "化学"}, {"name": "分子梭", "en": "molecular shuttle", "superfield": "化学"}, {"name": "分子结", "en": "molecular knot", "superfield": "化学"}, {"name": "分子钳", "en": "molecular clamp", "superfield": "化学"}, {"name": "分子马达", "en": "molecular motor", "superfield": "化学"}, {"name": "包结作用", "en": "encapsulation", "superfield": "化学"}, {"name": "卷曲", "en": "coiling", "superfield": "化学"}, {"name": "微泡体", "en": "vesicle", "superfield": "化学"}, {"name": "折叠体", "en": "foldamer", "superfield": "化学"}]}]}